3D Periodic Editor 3D Molecular And Reaction Editor Expert Editor Microsoft Quantum Editor EMSL Aerosol Workshop Editor Manual 3D Periodic Editor 3D Molecular And Reaction Editor Expert Editor Microsoft Quantum Editor EMSL Aerosol Workshop Editor Manual Results from an EMSL Arrows Calculation
| EMSL Arrows is a revolutionary approach to materials and chemical simulations that uses NWChem and chemical computational databases to make materials and chemical modeling accessible via a broad spectrum of digital communications including posts to web APIs, social networks, and traditional email. |
Molecular modeling software has previously been extremely complex, making it prohibative to all but experts in the field, yet even experts can struggle to perform calculations. This service is designed to be used by experts and non-experts alike. Experts can carry out and keep track of large numbers of complex calculations with diverse levels of theories present in their workflows. Additionally, due to a streamlined and easy-to-use input, non-experts can carry out a wide variety of molecular modeling calculations previously not accessible to them.
The id(s) for emsiles = C1(=C([C@H](C(=C[C]1N(=O)=O)N(=O)=O)O)N(=O)=O)C ^{-1} are: 4211
Use id=% instead of esmiles to print other entries.
mformula = C7H6N3O7
iupac = C1(=C([C@H](C(=C[C]1N(=O)=O)N(=O)=O)O)N(=O)=O)C anion
Search Links to Other Online Resources (may not be available):
- Google Structure Search
- EPA CompTox Database
- Chemical Entities of Biological Interest (ChEBI)
+==================================================+
|| Molecular Calculation ||
+==================================================+
Id = 4211
NWOutput = Link to NWChem Output (download)
Datafiles:
mo_orbital_nwchemarrows-2020-10-1-13-33-106839.out-942298-2020-10-1-15:37:2 (download)
homo-restricted.cube-942298-2020-10-1-15:37:2 (download)
lumo-restricted.cube-942298-2020-10-1-15:37:2 (download)
cosmo.xyz-942298-2020-10-1-15:37:2 (download)
image_resset: api/image_reset/4211
+----------------+
| Energetic Data |
+----------------+
Id = 4211
iupac = C1(=C([C@H](C(=C[C]1N(=O)=O)N(=O)=O)O)N(=O)=O)C anion
mformula = C7H6N3O7
inchi = InChI=1S/C7H6N3O7/c1-3-4(8(12)13)2-5(9(14)15)7(11)6(3)10(16)17/h2,7,11H,1H3/t7-/m0/s1
inchikey = DZAIWVHMHRTCRL-ZETCQYMHSA-N
esmiles = C1(=C([C@H](C(=C[C]1N(=O)=O)N(=O)=O)O)N(=O)=O)C ^{-1}
calculation_type = ovc
theory = dft
xc = pbe0
basis = 6-311++G(2d,2p)
charge,mult = -1 1
energy = -960.261443 Hartrees
enthalpy correct.= 0.167523 Hartrees
entropy = 119.524 cal/mol-K
solvation energy = -50.654 kcal/mol solvation_type = COSMO
Sitkoff cavity dispersion = 2.776 kcal/mol
Honig cavity dispersion = 9.578 kcal/mol
ASA solvent accesible surface area = 383.102 Angstrom2
ASA solvent accesible volume = 366.282 Angstrom3
+-----------------+
| Structural Data |
+-----------------+
JSmol: an open-source HTML5 viewer for chemical structures in 3D
Number of Atoms = 23
Units are Angstrom for bonds and degrees for angles
Type I J K L M Value
----------- ----- ----- ----- ----- ----- ----------
1 Stretch C1 C2 1.38496
2 Stretch C1 C6 1.42131
3 Stretch C1 C7 1.50005
4 Stretch C2 C3 1.50211
5 Stretch C2 N12 1.41487
6 Stretch C3 C4 1.48112
7 Stretch C3 O21 1.43330
8 Stretch C3 H23 1.09226
9 Stretch C4 C5 1.35101
10 Stretch C4 N13 1.42785
11 Stretch C5 C6 1.40712
12 Stretch C5 H11 1.07930
13 Stretch C6 N14 1.42225
14 Stretch C7 H8 1.08665
15 Stretch C7 H9 1.09058
16 Stretch C7 H10 1.08513
17 Stretch N12 O15 1.24190
18 Stretch N12 O16 1.22979
19 Stretch N13 O17 1.22836
20 Stretch N13 O18 1.22684
21 Stretch N14 O19 1.23194
22 Stretch N14 O20 1.23228
23 Stretch O21 H22 0.96270
24 Bend C2 C1 C6 116.13401
25 Bend C2 C1 C7 122.06241
26 Bend C6 C1 C7 121.57428
27 Bend C1 C2 C3 125.19291
28 Bend C1 C2 N12 122.00913
29 Bend C3 C2 N12 112.50045
30 Bend C2 C3 C4 109.48900
31 Bend C2 C3 O21 111.47639
32 Bend C2 C3 H23 109.35170
33 Bend C4 C3 O21 108.85688
34 Bend C4 C3 H23 109.65970
35 Bend O21 C3 H23 107.97869
36 Bend C3 C4 C5 122.81197
37 Bend C3 C4 N13 117.89983
38 Bend C5 C4 N13 119.28539
39 Bend C4 C5 C6 121.39807
40 Bend C4 C5 H11 119.68417
41 Bend C6 C5 H11 118.85281
42 Bend C1 C6 C5 121.20653
43 Bend C1 C6 N14 123.25462
44 Bend C5 C6 N14 115.35528
45 Bend C1 C7 H8 109.72343
46 Bend C1 C7 H9 111.20332
47 Bend C1 C7 H10 110.76238
48 Bend H8 C7 H9 106.71586
49 Bend H8 C7 H10 110.67776
50 Bend H9 C7 H10 107.66945
51 Bend C2 N12 O15 117.04612
52 Bend C2 N12 O16 121.21089
53 Bend O15 N12 O16 121.70635
54 Bend C4 N13 O17 119.23106
55 Bend C4 N13 O18 117.60260
56 Bend O17 N13 O18 123.16134
57 Bend C6 N14 O19 119.83546
58 Bend C6 N14 O20 118.11111
59 Bend O19 N14 O20 122.03827
60 Bend C3 O21 H22 104.20070
61 Dihedral C1 C2 C3 C4 22.61817
62 Dihedral C1 C2 C3 O21 -97.89036
63 Dihedral C1 C2 C3 H23 142.78663
64 Dihedral C1 C2 N12 O15 159.91088
65 Dihedral C1 C2 N12 O16 -22.25433
66 Dihedral C1 C6 C5 C4 4.96087
67 Dihedral C1 C6 C5 H11 -172.09857
68 Dihedral C1 C6 N14 O19 14.13502
69 Dihedral C1 C6 N14 O20 -167.25195
70 Dihedral C2 C1 C6 C5 -2.10275
71 Dihedral C2 C1 C6 N14 -176.94769
72 Dihedral C2 C1 C7 H8 -141.92902
73 Dihedral C2 C1 C7 H9 100.24287
74 Dihedral C2 C1 C7 H10 -19.44334
75 Dihedral C2 C3 C4 C5 -19.09669
76 Dihedral C2 C3 C4 N13 161.51922
77 Dihedral C2 C3 O21 H22 -69.07212
78 Dihedral C3 C2 C1 C6 -13.01679
79 Dihedral C3 C2 C1 C7 161.56022
80 Dihedral C3 C2 N12 O15 -14.12844
81 Dihedral C3 C2 N12 O16 163.70635
82 Dihedral C3 C4 C5 C6 7.18764
83 Dihedral C3 C4 C5 H11 -175.77695
84 Dihedral C3 C4 N13 O17 174.27219
85 Dihedral C3 C4 N13 O18 -6.51520
86 Dihedral C4 C3 C2 N12 -163.56763
87 Dihedral C4 C3 O21 H22 170.04907
88 Dihedral C4 C5 C6 N14 -179.80861
89 Dihedral C5 C4 C3 O21 102.99435
90 Dihedral C5 C4 C3 H23 -139.07673
91 Dihedral C5 C4 N13 O17 -5.13431
92 Dihedral C5 C4 N13 O18 174.07829
93 Dihedral C5 C6 C1 C7 -176.70843
94 Dihedral C5 C6 N14 O19 -160.98651
95 Dihedral C5 C6 N14 O20 17.62652
96 Dihedral C6 C1 C2 N12 173.72526
97 Dihedral C6 C1 C7 H8 32.35548
98 Dihedral C6 C1 C7 H9 -85.47263
99 Dihedral C6 C1 C7 H10 154.84116
100 Dihedral C6 C5 C4 N13 -173.43644
101 Dihedral C7 C1 C2 N12 -11.69774
102 Dihedral C7 C1 C6 N14 8.44663
103 Dihedral H11 C5 C4 N13 3.59897
104 Dihedral H11 C5 C6 N14 3.13195
105 Dihedral N12 C2 C3 O21 75.92383
106 Dihedral N12 C2 C3 H23 -43.39918
107 Dihedral N13 C4 C3 O21 -76.38975
108 Dihedral N13 C4 C3 H23 41.53917
109 Dihedral H22 O21 C3 H23 51.06310
+-----------------+
| Eigenvalue Data |
+-----------------+
Id = 4211
iupac = C1(=C([C@H](C(=C[C]1N(=O)=O)N(=O)=O)O)N(=O)=O)C anion
mformula = C7H6N3O7
InChI = InChI=1S/C7H6N3O7/c1-3-4(8(12)13)2-5(9(14)15)7(11)6(3)10(16)17/h2,7,11H,1H3/t7-/m0/s1
smiles = C1(=C([C@H](C(=C[C]1N(=O)=O)N(=O)=O)O)N(=O)=O)C
esmiles = C1(=C([C@H](C(=C[C]1N(=O)=O)N(=O)=O)O)N(=O)=O)C ^{-1}
theory = dft
xc = pbe0
basis = 6-311++G(2d,2p)
charge = -1
mult = 1
solvation_type = COSMO
twirl webpage = TwirlMol Link
image webpage = GIF Image Link
Eigevalue Spectra
--- -- --- 13.81 eV
-- -- -- -
-- -- -- -
7 - - - -
7 - - - -
9 - - - -
8 - - - -
8 - - - -
8 - - - -
9 - - - -
8 - - - -
6 - - - -
- - - - --
6 - - - -
---- ----
----------
---- ---- LUMO= -2.91 eV
HOMO= -6.36 eV ++++++++++
++++ ++++
8 + + + +
++++ ++++
++++ ++++
+++ ++ +++
++++ ++++
7 + + + +
+++ ++ +++
++++ ++++
++++++++++
++++++++++
++++++++++
++++++++++
++++ ++++
++++++++++
++++++++++
+++ ++ +++
-34.69 eV +++ ++ +++
spin eig occ ---------------------------- restricted -34.69 2.00 restricted -34.52 2.00 restricted -34.49 2.00 restricted -29.78 2.00 restricted -29.60 2.00 restricted -29.56 2.00 restricted -29.04 2.00 restricted -25.39 2.00 restricted -23.79 2.00 restricted -23.46 2.00 restricted -21.42 2.00 restricted -20.64 2.00 restricted -19.92 2.00 restricted -18.83 2.00 restricted -17.02 2.00 restricted -16.84 2.00 restricted -16.29 2.00 restricted -15.71 2.00 restricted -15.47 2.00 restricted -15.31 2.00 restricted -15.15 2.00 restricted -15.05 2.00 restricted -14.99 2.00 restricted -14.68 2.00 restricted -14.55 2.00 restricted -14.50 2.00 restricted -13.76 2.00 restricted -13.55 2.00 restricted -12.06 2.00 restricted -12.00 2.00 restricted -11.48 2.00 restricted -11.16 2.00 restricted -10.62 2.00 restricted -10.05 2.00 restricted -9.57 2.00 restricted -9.37 2.00 restricted -9.32 2.00 restricted -9.20 2.00 restricted -9.18 2.00 restricted -9.04 2.00 restricted -8.82 2.00 restricted -8.67 2.00 restricted -8.50 2.00 restricted -8.46 2.00 restricted -8.06 2.00 restricted -6.36 2.00 restricted -2.91 0.00 restricted -2.65 0.00 restricted -1.13 0.00 restricted 0.05 0.00 restricted 0.43 0.00 restricted 0.51 0.00 restricted 0.59 0.00 restricted 0.86 0.00 restricted 1.26 0.00 restricted 1.37 0.00 restricted 1.42 0.00 restricted 1.51 0.00 restricted 1.81 0.00 restricted 2.19 0.00 restricted 2.22 0.00 restricted 2.39 0.00 restricted 2.49 0.00 restricted 2.90 0.00 restricted 2.99 0.00 restricted 3.07 0.00 restricted 3.14 0.00 restricted 3.26 0.00 restricted 3.45 0.00 restricted 3.54 0.00 restricted 3.59 0.00 restricted 3.71 0.00 restricted 3.93 0.00 restricted 3.98 0.00 restricted 4.19 0.00 restricted 4.36 0.00 restricted 4.42 0.00 restricted 4.54 0.00 restricted 4.60 0.00 restricted 4.68 0.00 restricted 4.86 0.00 restricted 5.02 0.00 restricted 5.06 0.00 restricted 5.28 0.00 restricted 5.33 0.00 restricted 5.49 0.00 restricted 5.62 0.00 restricted 5.66 0.00 restricted 5.86 0.00 restricted 5.90 0.00 restricted 5.95 0.00 restricted 6.13 0.00 restricted 6.16 0.00 restricted 6.43 0.00 restricted 6.46 0.00 restricted 6.61 0.00 restricted 6.81 0.00 restricted 6.86 0.00 restricted 7.07 0.00 restricted 7.15 0.00 restricted 7.25 0.00 restricted 7.42 0.00 restricted 7.65 0.00 restricted 7.79 0.00 restricted 8.01 0.00 restricted 8.13 0.00 restricted 8.20 0.00 restricted 8.29 0.00 restricted 8.36 0.00 restricted 8.54 0.00 restricted 8.62 0.00 restricted 8.69 0.00 restricted 8.85 0.00 restricted 9.04 0.00 restricted 9.13 0.00 restricted 9.19 0.00 restricted 9.29 0.00 restricted 9.33 0.00 restricted 9.41 0.00 restricted 9.69 0.00 restricted 9.71 0.00 restricted 9.79 0.00 restricted 9.87 0.00 restricted 10.11 0.00 restricted 10.20 0.00 restricted 10.42 0.00 restricted 10.46 0.00 restricted 10.72 0.00 restricted 10.78 0.00 restricted 10.96 0.00 restricted 11.07 0.00 restricted 11.27 0.00 restricted 11.54 0.00 restricted 11.74 0.00 restricted 11.94 0.00 restricted 12.29 0.00 restricted 12.70 0.00 restricted 13.04 0.00 restricted 13.09 0.00 restricted 13.23 0.00 restricted 13.42 0.00 restricted 13.54 0.00 restricted 13.81 0.00
+----------------------------------------+ | Vibrational Density of States Analysis | +----------------------------------------+ Total number of frequencies = 69 Total number of negative frequencies = 0 Number of lowest frequencies = 19 (frequency threshold = 500 ) Exact dos norm = 63.000 Generating vibrational DOS Generating model vibrational DOS to have a proper norm 10.00 63.01 19.00 63.00 50.00 62.76 18.76 63.00 100.00 61.87 17.87 63.00 Generating IR Spectra Writing vibrational density of states (DOS) to vdos.dat Writing model vibrational density of states (DOS_FIXED) to vdos-model.dat Writing IR spectra to irdos.dat Temperature= 298.15 zero-point correction to energy = 95.564 kcal/mol ( 0.152291) vibrational contribution to enthalpy correction = 102.753 kcal/mol ( 0.163748) vibrational contribution to Entropy = 44.339 cal/mol-k hindered rotor enthalpy correction = 0.000 kcal/mol ( 0.000000) hindered rotor entropy correction = 0.000 cal/mol-k
DOS sigma = 10.000000
- vibrational DOS enthalpy correction = 0.163752 kcal/mol ( 102.756 kcal/mol)
- model vibrational DOS enthalpy correction = 0.163745 kcal/mol ( 102.752 kcal/mol)
- vibrational DOS Entropy = 0.000071 ( 44.444 cal/mol-k)
- model vibrational DOS Entropy = 0.000071 ( 44.430 cal/mol-k)
- original gas Energy = -960.261443 (-602573.148 kcal/mol)
- original gas Enthalpy = -960.093920 (-602468.026 kcal/mol, delta= 0.000)
- unajusted DOS gas Enthalpy = -960.093916 (-602468.024 kcal/mol, delta= 0.003)
- model DOS gas Enthalpy = -960.093923 (-602468.028 kcal/mol, delta= -0.002)
- original gas Entropy = 0.000190 ( 119.524 cal/mol-k,delta= 0.000)
- unajusted DOS gas Entropy = 0.000191 ( 119.628 cal/mol-k,delta= 0.104)
- model DOS gas Entropy = 0.000191 ( 119.615 cal/mol-k,delta= 0.091)
- original gas Free Energy = -960.150710 (-602503.662 kcal/mol, delta= 0.000)
- unadjusted DOS gas Free Energy = -960.150755 (-602503.691 kcal/mol, delta= -0.029)
- model DOS gas Free Energy = -960.150756 (-602503.691 kcal/mol, delta= -0.029)
- original sol Free Energy = -960.231433 (-602554.317 kcal/mol)
- unadjusted DOS sol Free Energy = -960.231479 (-602554.345 kcal/mol)
- model DOS sol Free Energy = -960.231479 (-602554.346 kcal/mol)
DOS sigma = 50.000000
- vibrational DOS enthalpy correction = 0.163655 kcal/mol ( 102.695 kcal/mol)
- model vibrational DOS enthalpy correction = 0.163923 kcal/mol ( 102.863 kcal/mol)
- vibrational DOS Entropy = 0.000074 ( 46.130 cal/mol-k)
- model vibrational DOS Entropy = 0.000074 ( 46.667 cal/mol-k)
- original gas Energy = -960.261443 (-602573.148 kcal/mol)
- original gas Enthalpy = -960.093920 (-602468.026 kcal/mol, delta= 0.000)
- unajusted DOS gas Enthalpy = -960.094013 (-602468.084 kcal/mol, delta= -0.058)
- model DOS gas Enthalpy = -960.093745 (-602467.916 kcal/mol, delta= 0.110)
- original gas Entropy = 0.000190 ( 119.524 cal/mol-k,delta= 0.000)
- unajusted DOS gas Entropy = 0.000193 ( 121.315 cal/mol-k,delta= 1.791)
- model DOS gas Entropy = 0.000194 ( 121.852 cal/mol-k,delta= 2.328)
- original gas Free Energy = -960.150710 (-602503.662 kcal/mol, delta= 0.000)
- unadjusted DOS gas Free Energy = -960.151654 (-602504.254 kcal/mol, delta= -0.592)
- model DOS gas Free Energy = -960.151641 (-602504.246 kcal/mol, delta= -0.584)
- original sol Free Energy = -960.231433 (-602554.317 kcal/mol)
- unadjusted DOS sol Free Energy = -960.232377 (-602554.909 kcal/mol)
- model DOS sol Free Energy = -960.232364 (-602554.901 kcal/mol)
DOS sigma = 100.000000
- vibrational DOS enthalpy correction = 0.163142 kcal/mol ( 102.373 kcal/mol)
- model vibrational DOS enthalpy correction = 0.164405 kcal/mol ( 103.166 kcal/mol)
- vibrational DOS Entropy = 0.000071 ( 44.332 cal/mol-k)
- model vibrational DOS Entropy = 0.000075 ( 46.805 cal/mol-k)
- original gas Energy = -960.261443 (-602573.148 kcal/mol)
- original gas Enthalpy = -960.093920 (-602468.026 kcal/mol, delta= 0.000)
- unajusted DOS gas Enthalpy = -960.094526 (-602468.406 kcal/mol, delta= -0.380)
- model DOS gas Enthalpy = -960.093263 (-602467.614 kcal/mol, delta= 0.412)
- original gas Entropy = 0.000190 ( 119.524 cal/mol-k,delta= 0.000)
- unajusted DOS gas Entropy = 0.000190 ( 119.517 cal/mol-k,delta= -0.007)
- model DOS gas Entropy = 0.000194 ( 121.990 cal/mol-k,delta= 2.466)
- original gas Free Energy = -960.150710 (-602503.662 kcal/mol, delta= 0.000)
- unadjusted DOS gas Free Energy = -960.151312 (-602504.040 kcal/mol, delta= -0.378)
- model DOS gas Free Energy = -960.151224 (-602503.985 kcal/mol, delta= -0.323)
- original sol Free Energy = -960.231433 (-602554.317 kcal/mol)
- unadjusted DOS sol Free Energy = -960.232036 (-602554.695 kcal/mol)
- model DOS sol Free Energy = -960.231947 (-602554.639 kcal/mol)
Normal Mode Frequency (cm-1) IR Intensity (arbitrary)
----------- ---------------- ------------------------
1 0.000 0.215
2 0.000 0.102
3 0.000 0.188
4 0.000 0.053
5 0.000 0.492
6 0.000 0.352
7 57.980 0.041
8 76.570 0.207
9 96.290 0.207
10 107.850 0.836
11 115.750 0.339
12 132.050 0.163
13 164.880 0.058
14 206.330 0.119
15 220.740 0.347
16 229.280 0.431
17 250.720 0.974
18 326.510 0.624
19 346.170 0.105
20 349.680 0.096
21 388.880 1.480
22 390.520 0.100
23 430.770 0.515
24 469.370 1.762
25 482.370 9.538
26 512.900 1.121
27 529.050 0.090
28 594.130 1.106
29 660.600 1.238
30 694.990 2.619
31 724.870 0.445
32 751.330 0.066
33 791.970 2.583
34 802.530 1.322
35 811.250 0.782
36 826.950 0.249
37 843.440 0.841
38 941.230 0.493
39 943.160 0.701
40 977.590 4.518
41 1018.860 14.428
42 1044.100 5.067
43 1056.550 10.583
44 1094.430 11.316
45 1157.990 4.858
46 1208.780 4.565
47 1226.000 0.178
48 1248.090 62.737
49 1305.010 174.006
50 1334.080 179.006
51 1360.420 13.917
52 1384.490 8.107
53 1411.010 3.482
54 1423.820 8.803
55 1431.170 12.371
56 1456.590 6.740
57 1467.810 1.918
58 1499.390 0.416
59 1536.100 20.176
60 1563.520 6.540
61 1590.610 24.949
62 1595.690 40.197
63 1680.770 27.001
64 3071.040 1.297
65 3076.720 1.364
66 3144.800 1.827
67 3179.920 1.021
68 3249.810 2.430
69 3813.650 3.184
No Hindered Rotor Data
+-------------------------------------+
| Reactions Contained in the Database |
+-------------------------------------+
Reactions Containing INCHIKEY = DZAIWVHMHRTCRL-ZETCQYMHSA-N
Reactionid Erxn(gas) Hrxn(gas) Grxn(gas) delta_Solv Grxn(aq) ReactionType Reaction
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KEYWORDs -
reaction: :reaction
chinese_room: :chinese_room
molecule: :molecule
nmr: :nmr
predict: :predict
submitesmiles: :submitesmiles
nosubmitmissingesmiles
resubmitmissingesmiles
submitmachines: :submitmachines
useallentries
nomodelcorrect
eigenvalues: :eigenvalues
frequencies: :frequencies
nwoutput: :nwoutput
xyzfile: :xyzfile
alleigs: :alleigs
allfreqs: :allfreqs
reactionenumerate:
energytype:[erxn(gas) hrxn(gas) grxn(gas) delta_solvation grxn(aq)] :energytype
energytype:[kcal/mol kj/mol ev cm-1 ry hartree au] :energytype
tablereactions:
reaction: ... :reaction
reaction: ... :reaction
...
:tablereactions
tablemethods:
method: ... :method
method: ... :method
...
:tablemethods
:reactionenumerate
rotatebonds
xyzinput:
label: :label
xyzdata:
... xyz data ...
:xyzdata
:xyzinput
submitHf: :submitHf
nmrexp: :nmrexp
findreplace: old text | new text :findreplace
listnwjobs
fetchnwjob: :fetchnwjob
pushnwjob: :pushnwjob
printcsv: :printcsv
printeig: :printeig
printfreq: :printfreq
printxyz: :printxyz
printjobinfo: :printjobinfo
printnwout: :printnwout
badids: :badids
hup_string:
database:
table:
request_table:
listallesmiles
queuecheck
This software service and its documentation were developed at the Environmental Molecular Sciences Laboratory (EMSL) at Pacific Northwest National Laboratory, a multiprogram national laboratory, operated for the U.S. Department of Energy by Battelle under Contract Number DE-AC05-76RL01830. Support for this work was provided by the Department of Energy Office of Biological and Environmental Research, and Department of Defense environmental science and technology program (SERDP). THE SOFTWARE SERVICE IS PROVIDED "AS IS", WITHOUT WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO THE WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE AND NONINFRINGEMENT. IN NO EVENT SHALL THE AUTHORS OR COPYRIGHT HOLDERS BE LIABLE FOR ANY CLAIM, DAMAGES OR OTHER LIABILITY, WHETHER IN AN ACTION OF CONTRACT, TORT OR OTHERWISE, ARISING FROM, OUT OF OR IN CONNECTION WITH THE SOFTWARE SERVICE OR THE USE OR OTHER DEALINGS IN THE SOFTWARE SERVICE.